Mechanochemical reactions of coordination polymers by grinding with KBr.

نویسندگان

  • Mangayarkarasi Nagarathinam
  • Anjana Chanthapally
  • Saul H Lapidus
  • Peter W Stephens
  • Jagadese J Vittal
چکیده

Grinding of a one-dimensional (1-D) ladder coordination polymer (CP), [Zn(μ-CH(3)CO(2))(CF(3)CO(2))bpe] (1), and a hydrogen-bonded 1-D CP, [Cd(CH(3)CO(2))(2)bpe(H(2)O)] (2), with KBr resulted in the exchange of carboxylate by bromide ions and the formation of 1-D zigzag and 2-D CPs respectively.

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عنوان ژورنال:
  • Chemical communications

دوره 48 20  شماره 

صفحات  -

تاریخ انتشار 2012